Commonly occurring product ions for PE(P-18:0/20:4(6E,8Z,11Z,14Z)(5OH[S])) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
766.5392Precursor ion [M-H]-
516.2732Loss of plasmenyl group (RCH=CH2) from [M-H]-
498.2626Neutral loss of plasmenyl group RCH=CHOH) from [M-H]-
464.3147Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
446.3041Neutral loss of sn2 RCOOH group from [M-H]-
319.2279sn2 RCOO- ion
275.2380Loss of CO2 from sn2 RCOO- ion (PUFA)
152.9958Glycerol-3-phosphate ion with loss of H2O
140.0118Ethanolamine phosphate ion
122.0013Ethanolamine phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases