Commonly occurring product ions for PC(O-14:0/11:0) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
656.4427Precursor ion [M.chloride]-
606.4504Loss of CH3 and chloride from precursor ion
535.3769Loss of choline and chloride from precursor ion
438.2990Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
420.2884Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
349.2149Loss of choline, chloride and neutral loss of sn2 RCOOH group from precursor ion
224.0693Glycerophosphocholine with loss of CH3 and H2O
185.1547sn2 RCOO- ion
168.0431Phosphocholine with loss of CH3
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases