Commonly occurring product ions for PC(P-18:1(9Z)/22:1(13Z)) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
860.6305Precursor ion [M.chloride]-
810.6382Loss of CH3 and chloride from precursor ion
739.5647Loss of choline and chloride from precursor ion
490.3303Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
472.3197Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
401.2462Loss of choline, chloride and neutral loss of sn2 RCOOH group from precursor ion
337.3112sn2 RCOO- ion
224.0693Glycerophosphocholine with loss of CH3 and H2O
168.0431Phosphocholine with loss of CH3
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases