Commonly occurring product ions for PC(19:0/11:0) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
740.5003Precursor ion [M.chloride]-
690.5079Loss of CH3 and chloride from precursor ion
619.4344Loss of choline and chloride from precursor ion
522.3565Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
504.3460Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
410.2313Loss of sn1 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
392.2208Neutral loss of sn1 RCOOH group, loss of CH3 and chloride from precursor ion
297.2799sn1 RCOO- ion
224.0693Glycerophosphocholine with loss of CH3 and H2O
185.1547sn2 RCOO- ion
168.0431Phosphocholine with loss of CH3
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases